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Title: cis-Dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-kappaP)iridium(III) tetrafluoridoborate, formed by reaction of (cycloocta-1,5-diene)bis(triphenylphosphine)iridium tetrafluoridoborate with carbonyl fluoride in dichloromethane solution.
Authors: Harding, D. A.
Hope, E. G.
Solan, G. A.
Fawcett, J.
First Published: Jul-2007
Citation: ACTA CRYSTALLOGR C, 2007, 63 (Pt 7), pp. m321-m322
Abstract: The reaction between carbonyl fluoride and [Ir(COD)(PPh(3))(2)]BF(4) (COD is cycloocta-1,5-diene) in dichloromethane solution affords the novel title iridium salt, [IrCl(2)(C(18)H(15)P)(2)(CO)(2)]BF(4). The cation lies across a twofold rotation axis in the space group P2(1)2(1)2 and its structure confirms the presence in a cis relationship of two metal-bound chlorides, while the phosphine ligands occupy a trans pair of sites. The anion also lies across a twofold rotation axis, and the F atoms are disordered over two sets of sites.
DOI Link: 10.1107/S0108270107025358
ISSN: 0108-2701
Type: Journal Article
Appears in Collections:Published Articles, Dept. of Chemistry

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