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Title: Effect of electrolyte concentration on the viscosity and voltammetry of supercritical solutions.
Authors: Abbott, AP
Hope, EG
Palmer, DJ
First Published: 15-Oct-2005
Citation: ANAL CHEM, 2005, 77 (20), pp. 6702-6708
Abstract: The viscosity of a supercritical electrolyte solution is measured for the first time using a modified quartz crystal microbalance, and it is shown that ionic solvation leads to a significant structuring of the solvent and an appreciable increase in solution viscosity. Voltammetric investigations in the electrolyte solutions are used to confirm the magnitude of the viscosity changes, and these account for the appreciably lower than expected peak currents.
DOI Link: 10.1021/ac050883i
ISSN: 0003-2700
Type: Journal Article
Appears in Collections:Published Articles, Dept. of Chemistry

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