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Title: Internal electron transfer in multi-site redox enzymes is accessed by laser excitation of thiouredopyrene-3,6,8-trisulfonate (TUPS).
Authors: Heyes, DJ
Quinn, AM
Cullis, PM
Lee, M
Munro, AW
Scrutton, NS
First Published: 7-Mar-2009
Citation: CHEM COMMUN (CAMB), 2009 (9), pp. 1124-1126
Abstract: We demonstrate that thiouredopyrene-3,6,8-trisulfonate (TUPS), a photoactivatable reagent, can rapidly inject electrons into complex redox enzymes, enabling studies of the kinetics of internal electron that are not accessible using conventional rapid mixing, stopped-flow methods.
DOI Link: 10.1039/b820386e
ISSN: 1359-7345
Type: Journal Article
Appears in Collections:Published Articles, Dept. of Chemistry

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