Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/18158
Title: Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4(-) and comparison with imidazolium based systems.
Authors: Abood, HM
Abbott, AP
Ballantyne, AD
Ryder, KS
First Published: 28-Mar-2011
Citation: CHEM COMMUN (CAMB), 2011, 47 (12), pp. 3523-3525
Abstract: The addition of a simple amide to AlCl(3) causes the formation of a liquid of the form [AlCl(2)·nAmide](+) AlCl(4)(-). The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.
DOI Link: 10.1039/c0cc04989a
eISSN: 1364-548X
Links: http://hdl.handle.net/2381/18158
Type: Journal Article
Appears in Collections:Published Articles, Dept. of Chemistry

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