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Title: trans-Bis{1-[2-(2,6-diisopropyl-anilino)phenyl]-3-isopropyl-imidazolin-2-ylidenyl-κC}diiodidopalladium(II) benzene disolvate.
Authors: Daly, C. G.
Singh, K.
Cross, W. B.
First Published: 1-Jun-2011
Publisher: International Union of Crystallography
Citation: Acta Crystallographica Section E: Structure Reports Online, 2011, 67 (Pt 6), p. m668
Abstract: In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I-Pd-C-N torsion angles of -81.1 (6) and -78.2 (5)°. The Pd-carbene and Pd-I distances are 2.016 (6) and 2.5971 (10) Å, respectively.
DOI Link: 10.1107/S1600536811015431
eISSN: 1600-5368
Version: Publisher Version
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © the authors, 2011. Deposited with reference to the publisher’s archiving policy available on the SHERPA/RoMEO website.
Appears in Collections:Published Articles, Dept. of Chemistry

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