Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/28290
Title: Isoprene emissions in Africa inferred from OMI observations of formaldehyde columns
Authors: Marais, E.A.
Jacob, D.J.
Kurosu, T.P.
Chance, K.
Murphy, J.G.
Reeves, C.
Mills, G.
Casadio, S.
Millet, D.B.
Barkley, Michael P.
Paulot, F.
Mao, J.
First Published: 2012
Publisher: Copernicus GmbH (Copernicus Publications) on behalf of the European Geosciences Union (EGU).
Citation: Atmospheric Chemistry and Physics, 2012, 12 (14), pp. 6219-6235 (17)
Abstract: We use 2005–2009 satellite observations of formaldehyde (HCHO) columns from the OMI instrument to infer biogenic isoprene emissions at monthly 1 × 1° resolution over the African continent. Our work includes new approaches to remove biomass burning influences using OMI absorbing aerosol optical depth data (to account for transport of fire plumes) and anthropogenic influences using AATSR satellite data for persistent small-flame fires (gas flaring). The resulting biogenic HCHO columns (Ω[subscript HCHO]) from OMI follow closely the distribution of vegetation patterns in Africa. We infer isoprene emission (E[subscript ISOP]) from the local sensitivity S = ΔΩ[subscript HCHO] / ΔE[subscript ISOP] derived with the GEOS-Chem chemical transport model using two alternate isoprene oxidation mechanisms, and verify the validity of this approach using AMMA aircraft observations over West Africa and a longitudinal transect across central Africa. Displacement error (smearing) is diagnosed by anomalously high values of S and the corresponding data are removed. We find significant sensitivity of S to NO[subscript x] under low-NO[subscript x] conditions that we fit to a linear function of tropospheric column NO[subscript 2]. We estimate a 40% error in our inferred isoprene emissions under high-NO[subscript x] conditions and 40–90% under low-NO[subscript x] conditions. Our results suggest that isoprene emission from the central African rainforest is much lower than estimated by the state-of-the-science MEGAN inventory.
DOI Link: 10.5194/acp-12-6219-2012
ISSN: 1680-7316
eISSN: 1680-7324
Links: http://www.atmos-chem-phys.net/12/6219/2012/acp-12-6219-2012.html
http://hdl.handle.net/2381/28290
Version: Publisher Version
Status: Peer-reviewed
Type: Journal Article
Rights: © Author(s) 2012. This is an open-access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Appears in Collections:Published Articles, Dept. of Physics and Astronomy

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