Please use this identifier to cite or link to this item:
Title: Preparation of single enantiomers of chiral at metal bis-cyclometallated iridium complexes
Authors: Davies, David L.
Singh, Kuldip
Singh, Shalini
Villa-Marcos, Barbara
First Published: 6-Jun-2013
Publisher: Royal Society of Chemistry
Citation: Chemical Communications (Camb), 2013, 49 (58), pp. 6546-6548
Abstract: Reaction of [Ir(C^N)[subscript 2]Cl][subscript 2] with chiral bidentate N^OH ligands provides complexes [Ir(C^N)[subscript 2](N^O)] as a 1 : 1 mixture of diastereomers which can be separated by crystallisation. A pure diastereomer can be converted to [Ir(C^N)[subscript 2](bipy)][CF[subscript 3]CO[subscript 2]] with complete retention of stereochemistry at the metal.
DOI Link: 10.1039/c3cc43121e
ISSN: 1359-7345
eISSN: 1364-548X
Version: Publisher Version
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © 2013, The Royal Society of Chemistry. Deposited with reference to the publisher’s archiving policy available on the SHERPA/RoMEO website.
Appears in Collections:Published Articles, Dept. of Chemistry

Files in This Item:
File Description SizeFormat 
c3cc43121e.pdfPublished (publisher PDF)1.34 MBUnknownView/Open

Items in LRA are protected by copyright, with all rights reserved, unless otherwise indicated.