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Title: Electrochromic enhancement of latent fingerprints by poly(3,4-ethylenedioxythiophene)
Authors: Sapstead (nee Brown), Rachel Marie
Hillman, A. Robert
First Published: 2-May-2012
Publisher: Royal Society of Chemistry
Citation: Physical Chemistry Chemical Physics, 2012,14, 8653-8661
Abstract: Spatially selective electrodeposition of poly-3,4-ethylenedioxythiophene (PEDOT) thin films on metallic surfaces is shown to be an effective means of visualizing latent fingerprints. The technique exploits the fingerprint deposit as an insulating mask, such that electrochemical processes (here, polymer deposition) may only take place on deposit-free areas of the surface between the ridges of the fingerprint deposit; the end result is a negative image of the fingermark. Use of a surfactant (sodium dodecylsulphate, SDS) to solubilise the EDOT monomer allows the use of an aqueous electrolyte. Electrochemical (coulometric) data provide a total assay of deposited material, yielding spatially averaged film thicknesses, which are commensurate with substantive filling of the trenches between fingerprint deposit ridges, but not overfilling to the extent that the ridge detail is covered. This is confirmed by optical microscopy and AFM images, which show continuous polymer deposition within the trenches and good definition at the ridge edges. Stainless steel substrates treated in this manner and transferred to background electrolyte (aqueous sulphuric acid) showed enhanced fingerprints when the contrast between the polymer background and fingerprint deposit was optimised using the electrochromic properties of the PEDOT films. The facility of the method to reveal fingerprints of various ages and subjected to plausible environmental histories was demonstrated. Comparison of this enhancement methodology with commonly used fingerprint enhancement methods (dusting with powder, application of wet powder suspensions and cyanoacrylate fuming) showed promising performance in selected scenarios of practical interest.
DOI Link: 10.1039/c2cp40733g
ISSN: 1463-9076
eISSN: 1463-9084
Version: Publisher Version
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © the Owner Societies, 2012. Deposited with reference to the publisher’s archiving policy available on the SHERPA/RoMEO website.
Appears in Collections:Published Articles, Dept. of Chemistry

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