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Title: Atropisomerism in a thermally switchable, cyclometallated iridium complex
Authors: Howarth, Ashlee J.
Davies, David L.
Lelj, Francesco
Wolf, Michael O.
Patrick, Brian O.
First Published: 25-Jun-2012
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 2012, 41 (34), pp. 10150-10152
Abstract: Two stable diastereomeric atropisomers of a cyclometallated iridium complex containing a pyrene functionalized pyridine imine ligand have been isolated. These are the first fully characterized examples of metal containing atropisomers in which the rotational axis is not between two chelating atoms. The atropisomers can be converted thermally via a rocking motion of the pyrene moiety.
DOI Link: 10.1039/c2dt31120h
ISSN: 1477-9226
eISSN: 1477-9234
Version: Post-print
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © 2012, Royal Society of Chemistry. Deposited with reference to the publisher’s archiving policy available on the SHERPA/RoMEO website.
Appears in Collections:Published Articles, Dept. of Chemistry

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