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Title: Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride
Authors: Geary, Gemma
Hope, Eric G.
Singh, Kuldip
Stuart, Alison M.
First Published: 18-Oct-2013
Citation: Chemical Communications, 2013, 49 (81), pp. 9263-9265
Abstract: The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as an electrophilic fluorinating reagent for the first time to monofluorinate 1,3-ketoesters and difluorinate 1,3-diketones in good isolated yields.
DOI Link: 10.1039/c3cc44792h
ISSN: 1359-7345
eISSN: 1364-548X
Version: Post-print
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © The Royal Society of Chemistry 2013.
Description: The file associated with this record is under a 12-month embargo from publication in accordance with the publisher's self-archiving policy, available at The full text may be available through the publisher links provided above.
Appears in Collections:Published Articles, Dept. of Chemistry

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