Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/33651
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dc.contributor.authorDigman, Timothy.en
dc.date.accessioned2015-11-19T08:44:32Z-
dc.date.available2015-11-19T08:44:32Z-
dc.date.issued1984en
dc.identifier.urihttp://hdl.handle.net/2381/33651-
dc.description.abstractThe reaction between Fe(phen)32+ and Nu (Nu = OH-, CN-) in aqueous methanol mixtures was analysed, in terms of H into initial state-transition state contributions. The racemisation of the (-) Fe(phen)32+ cation in aqueous DMSO and aqueous methanol mixtures was analysed, in terms of G, into initial state-transition state contributions. Fe(mppm)32+ was resolved, and the kinetics of racemisation were investigated. Fe(5NO2 phen)32+ was resolved and found to racemise very quickly at 25°C. Ru(5NO2 phen)32+ was resolved, and showed no tendency to racemise at 25°C. Attempts to resolve Fe(btz)32+ and Ru(btz)32+ were unsuccessful. The reactions between Fe(btz)32+ and R (R = OH-, H+, Hg2+, Cd2+, S2,O82-, phen, bipy) are reported. The stability constants of Fe(btz)32+, Agbtz+, Cdbtz2+ and Hgbtz2+ were measured. The solvatochromism of Mo(CO)4 btz, Mo(CO)4 bipym, PNA, DMIA, Fe(btz)2 (CN)2 are reported. The solvatochromism of Mo(CO)4 btz, PNA and DMIA were analysed into ground state-excited state contributions. The structure of Mo(C0)4 btz is described. The solvolysis of Mo(CO)4 btz was analysed in terms of initial state-transition state contributions. The reactions between Mo(CO)4 btz and Q (Q = Hg2+, HgC12, PtC142-, In3+, Cd2+, MeI, PtC12, PPh3, P(OPh)3, Mo(CO)4 (pip)2) are reported. The reactions between Mo(CO)4 (pip)2. and R (R = btz, dt, (btz + bipy), PtC12btz) are reported. The preparation of PtC12btz is described.en
dc.language.isoenen
dc.rightsCopyright © the author. All rights reserved.en
dc.sourceProQuesten
dc.titleThe effects of solvents on reactivities, kinetics and charge transfer spectra of some transition metal diimine complexes.en
dc.typeThesisen
dc.type.qualificationlevelDoctoralen
dc.type.qualificationnamePh.D.en
dc.date.award1984en
dc.publisher.departmentChemistryen
dc.publisher.institutionUniversity of Leicesteren
dc.identifier.proquestU344349en
dc.identifier.cataloguecontrolx75003640xen
Appears in Collections:Theses, Dept. of Chemistry
Leicester Theses

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