Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/33768
Full metadata record
DC FieldValueLanguage
dc.contributor.authorJudkins, Brian David.en
dc.date.accessioned2015-11-19T08:45:58Z-
dc.date.available2015-11-19T08:45:58Z-
dc.date.issued1981en
dc.identifier.urihttp://hdl.handle.net/2381/33768-
dc.description.abstractThe first part of this work is an investigation of the reason for the abnormally high barrier to rotation around the N-N bond in certain N-quinolone substituted sulphenamides. Some mechanisms by which diastereoisomers of the above compounds could interconvert are also examined. Extension of this work lead to resolution of N-benzyl-N-(1,2-dihydro-2-oxoquinolin-1-yl) glycine as a result of the N-N chiral axis. The thermal stability of some heterocyclic sulphenamides is also investigated. A study of the reaction of some alkylhydrazines with arylsulphenyl chlorides is described and some mechanisms proposed for the fragmentation of the intermediate sulphenylhydrazides. The trapping of dinitrobenzenesulphenylnitrene with alkenes and other reagents is described as well as a study of the stereospecificity of its addition to cis-l-phenylpropene. The generation and attempted trapping of other sulphenylnitrenes is also investigated.en
dc.language.isoenen
dc.rightsCopyright © the author. All rights reserved.en
dc.sourceProQuesten
dc.titleRotational barriers in heterocyclic sulphenamides: Intermolecular trapping of sulphenylnitrenes.en
dc.typeThesisen
dc.type.qualificationlevelDoctoralen
dc.type.qualificationnamePh.D.en
dc.date.award1981en
dc.publisher.departmentChemistryen
dc.publisher.institutionUniversity of Leicesteren
dc.identifier.proquestU315742en
dc.identifier.cataloguecontrolx752943722en
Appears in Collections:Theses, Dept. of Chemistry
Leicester Theses

Files in This Item:
File Description SizeFormat 
U315742.pdf13.13 MBAdobe PDFView/Open


Items in LRA are protected by copyright, with all rights reserved, unless otherwise indicated.