Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/38078
Title: Anodic dissolution of metals in ionic liquids
Authors: Abbott, Andrew P.
Frisch, Gero
Hartley, Jennifer
Karim, Wrya O.
Ryder, Karl S.
First Published: 1-Dec-2015
Publisher: Elsevier
Citation: Progress in Natural Science: Materials International, 2015, 25 (6), pp. 595-602
Abstract: The anodic dissolution of metals is an important topic for battery design, material finishing and metal digestion. Ionic liquids are being used in all of these areas but the research on the anodic dissolution is relatively few in these media. This study investigates the behaviour of 9 metals in an ionic liquid [C4mim][Cl] and a deep eutectic solvent, Ethaline, which is a 1:2 mol ratio mixture of choline chloride and ethylene glycol. It is shown that for the majority of metals studied a quasi-passivation of the metal surface occurs, primarily due to the formation of insoluble films on the electrode surface. The behaviour of most metals is different in [C4mim][Cl] to that in Ethaline due in part to the differences in viscosity. The formation of passivating salt films can be decreased with stirring or by increasing the electrolyte temperature, thereby increasing ligand transport to the electrode surface.
DOI Link: 10.1016/j.pnsc.2015.11.005
ISSN: 1002-0071
Links: http://www.sciencedirect.com/science/article/pii/S1002007115001239
http://hdl.handle.net/2381/38078
Version: Publisher Version
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © the authors, 2015. This is an open-access article distributed under the terms of the Creative Commons Attribution-Non Commercial-No Derivatives License (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
Appears in Collections:Leicester Theses
Published Articles, Dept. of Chemistry

Files in This Item:
File Description SizeFormat 
1-s2.0-S1002007115001239-main.pdfPublished (publisher PDF)2.02 MBAdobe PDFView/Open


Items in LRA are protected by copyright, with all rights reserved, unless otherwise indicated.