Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/43765
Title: Chemical composition and source identification of PM10 in five North Western European cities
Authors: Hama, SML
Cordell, RL
Staelens, J
Mooibroek, D
Monks, PS
First Published: 19-Jul-2018
Publisher: Elsevier
Citation: ATMOSPHERIC RESEARCH, 2018, 214, pp. 135-149 (15)
Abstract: Particulate matter (PM) is a complex, heterogeneous mixture that changes in time and space. It has many different chemical constituents, several of which have been identified as potential contributors to toxicity, and varying physical characteristics. Identifying and quantifying the effects of specific components or source-related combinations on human health, particularly when particles interact with other co-pollutants, therefore represents one of the most challenging areas of environmental health research. Owing to the importance of PM10 chemical composition in understanding particulate pollution sources, 1942 PM10 samples were simultaneously collected at five sites (four urban background sites located in Amsterdam (AD), Antwerp (AP), Leicester (LE) and Lille (LL), and one industrial site at Wijk aan Zee (WZ)) across North-West Europe from April 2013 to May 2014, and chemical species and sources of PM10 were investigated. PM10 samples were chemically analysed for water-soluble ions (NO3−, SO42−, Cl−, NH4+, Na+, K+, Mg2+, and Ca2+), carbonaceous species (OC, and EC), minerals (Al, Ca, Fe, Ti, and K), trace elements (As, Ba, Cd, Cr, Cu, Mn, Mo, Ni, Pb, Sb, V, and Zn), and monosaccharides (levoglucosan, galactosan, and mannosan). Spatial and seasonal variations of the atmospheric concentrations of species were also investigated. In order to reconstruct the particle mass, the determined constituents were classified into seven classes as follows: mineral dust (MD), organic matter (OM), elemental carbon (EC), trace elements (TE), sea salt (SS), secondary inorganic aerosol (SIA), and monosaccharides (MSS). Strong correlations (R2 = 0.88–0.96) were found between chemically determined and gravimetrically measured PM10 masses for all sites. According to chemical mass closure, the major components of PM10 were SIA, followed by OM and MD at the four urban sites, and the major components of PM10 were SIA, followed by MD and SS at an industrially influenced site. SIA dominated the PM10 profiles at all sites, accounting for 36, 35, 32, 36, and 32% at AD, AP, LE, LL, and WZ, respectively. Five PCA factors explained 67, 80, 76, and 74% of the variance of the data at AD, AP, LL and WZ respectively. In addition, four factors are extracted for LE site explaining 71% of the variance. The PCA results showed that secondary aerosols, biomass burning, and traffic emissions were the most important sources across North-West Europe.
DOI Link: 10.1016/j.atmosres.2018.07.014
ISSN: 0169-8095
eISSN: 1873-2895
Links: https://www.sciencedirect.com/science/article/pii/S0169809518302175?via%3Dihub
http://hdl.handle.net/2381/43765
Embargo on file until: 19-Jul-2019
Version: Post-print
Status: Peer-reviewed
Type: Journal Article
Rights: Copyright © © 2018 Elsevier B.V. After an embargo period this version of the paper will be an open-access article distributed under the terms of the Creative Commons Attribution-Non Commercial-No Derivatives License (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
Description: The file associated with this record is under embargo until 12 months after publication, in accordance with the publisher's self-archiving policy. The full text may be available through the publisher links provided above.
Appears in Collections:Published Articles, College of Science and Engineering

Files in This Item:
File Description SizeFormat 
PM10+paper+revised.+17.06.2018.pdfPost-review (final submitted author manuscript)3.77 MBAdobe PDFView/Open


Items in LRA are protected by copyright, with all rights reserved, unless otherwise indicated.