Please use this identifier to cite or link to this item:
Title: Dissociation and suppressed ionization of H2O molecules embedded in He clusters: The role of the cluster as a cage.
Authors: Kanaev, A.V.
Museur, L.
Laarmann, Tim
Monticone, S.
Castex, M.C.
von Haeften, Klaus
Möller, Thomas
First Published: 8-Dec-2001
Publisher: American Institute of Physics.
Citation: Journal of Chemical Physics, 2001, 115 (22), pp.10248-10253.
Abstract: Electronic structure and energy transfer in H2O doped HeN clusters (N≈10)4 is studied with photoexcitation in the spectral range of 140–40 nm (9–30 eV). The reaction dynamics is investigated by fluorescence of neutral OH* and H* and ionic H2O+ fragments. The rotational temperature of embedded water molecules has been estimated from the 124 nm line shape (3pa1 C1 B1←1b1 X˜1 A1 transition!. Two different temperatures (T1≤5 K and T2≈30K) have been found. We propose that the lower temperature (T1) is due to completely thermalized water molecules trapped inside helium clusters, while the warmer molecules (T2) are formed if they are first captured by helium clusters but then leave the clusters again. Predissociation of H2O with excitation below the ionization limit (λexc.100 nm) is found to be unaffected by the cluster environment. On the other hand, the ionization (λexc,100 nm) seems to be suppressed inside helium clusters in favor of the fragmentation into neutral products.
Type: Article
Description: This is the version as published by American Institute of Physics.
Appears in Collections:Published Articles, Dept. of Physics and Astronomy

Files in This Item:
File Description SizeFormat 
dissociation.pdf88.41 kBAdobe PDFView/Open

Items in LRA are protected by copyright, with all rights reserved, unless otherwise indicated.