Please use this identifier to cite or link to this item: http://hdl.handle.net/2381/579
Title: Intramolecular nucleophilic catalysis and the exceptional reactivity of N-benzyloxycarbonyl alpha-aminophosphonochloridates.
Authors: Cullis, P. M.
Harger, M. J. P.
First Published: 2002
Citation: Journal of the Chemical Society: Perkin Transactions 2, 2002, (9), pp.1538-1543
Abstract: The chloridate BnOCONHCH2P(O)(OMe)Cl is 103–104 times more reactive than ClCH2P(O)(OMe)Cl in substitution with PriOH; the α,α-dimethyl analogue is no less reactive and the N-methyl derivative is more reactive; nucleophilic participation (catalysis) by the carbamate group is implicated.
DOI Link: 10.1039/b204935j
ISSN: 1472-779X
Links: http://hdl.handle.net/2381/579
http://pubs.rsc.org/en/Content/ArticleLanding/2002/P2/b204935j
Type: Article
Appears in Collections:Published Articles, Dept. of Chemistry

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