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|Title:||Intramolecular nucleophilic catalysis and the exceptional reactivity of N-benzyloxycarbonyl alpha-aminophosphonochloridates.|
|Authors:||Cullis, P. M.|
Harger, M. J. P.
|Citation:||Journal of the Chemical Society: Perkin Transactions 2, 2002, (9), pp.1538-1543|
|Abstract:||The chloridate BnOCONHCH2P(O)(OMe)Cl is 103–104 times more reactive than ClCH2P(O)(OMe)Cl in substitution with PriOH; the α,α-dimethyl analogue is no less reactive and the N-methyl derivative is more reactive; nucleophilic participation (catalysis) by the carbamate group is implicated.|
|Appears in Collections:||Published Articles, Dept. of Chemistry|
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