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First PublishedTitleAuthor(s)Type
1995Cleavage of both alkyl C-H bonds and aryl C-F bonds and concomitant C-C bond formation in a pentamethylcyclopentadienylrhodium phosphine complex: X-ray structure of [η-CMe[CHC FP(CF)CH] -1,3}RhCl]BFAtherton, MJ; Fawcett, J; Holloway, JH; Hope, EG; Karaçar, A; Russell, DR; Saunders, GCJournal Article
21-Dec-1995Pentafluorophenylphosphine complexes of Rhodium(I): Extended x-ray absorption fine structure studies of [{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x=0-2) and [{Rh[(C6F5)(2)PCH2CH2P(C6F5)(2)](mu-Cl)}(2)]. Crystal structures of [RhCl(PPh(3)){(C6F5)(2)PCH2CH2P(C6F5)(2)}]center dot C4H8O and (C6F5)(2)PCH2CH2P(C6F5)(2)Atherton, MJ; Coleman, KS; Fawcett, J; Holloway, JH; Hope, EG; Karacar, A; Peck, LA; Saunders, GCJournal Article
15-Oct-1996Cis-dichloro(triethylphosphine-P) [tris(2,6-difluorophenyl)phosphite-P]platinum(II)Fawcett, J; Holloway, JH; Hope, EG; Saunders, GC; Atherton, MJJournal Article
7-Jul-1997Pentafluorophenylphosphine complexes of platinum(II); Crystal structure of trans-[PtCl2(PEt3){PPh2(C6F5)}]Atherton, MJ; Fawcett, J; Holloway, JH; Hope, EG; Russell, DR; Saunders, GCJournal Article
15-May-1998Remarkable regioselectivity in the reaction between [(eta(5)-C5Me4H)RhCl(mu-Cl)](2) and (C6F5)(2)PCH2CH2P(C6F5)(2): synthesis of a chiral-at-metal rhodium complex cation via carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formationAtherton, MJ; Holloway, JH; Hope, EG; Saunders, GCJournal Article
7-Aug-1996Carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation in eta(5)-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; Crystal structures of [M(eta(5)-C(5)Me(5))Cl{(C6F5)(2)PCH2CH2P-(C6F5)(2)}](BF4-)-B-+ (M=Rh or Ir)Atherton, MJ; Fawcett, J; Holloway, JH; Hope, EG; Karacar, A; Russell, DR; Saunders, GCJournal Article
20-Jun-1999Intermediates and action effects in the activation of carbon-fluorine bonds by eta(5)-pentamethylcyclopentadienylrhodium halide complexes; crystal structure of [{eta(5)-C5Me3[CH2C6F4P(C6F5)CH2](2)-1,3}RhBr](+)center dot Br-Atherton, MJ; Fawcett, J; Holloway, JH; Hope, EG; Russell, DR; Saunders, GCJournal Article
25-Mar-1998Activation of C-F and C-H bonds by polyalkylcyclopentadienylrhodium complexes: crystal structure of [(eta(5)-C5Me4Et)RhCl{(C6F5)(2)PCH2CH2P(C6F5)(2)}](+).BF4-Atherton, MJ; Fawcett, J; Holloway, JH; Hope, EG; Martin, SM; Russell, DR; Saunders, GCJournal Article
1-Jan-1996Tris(pentafluorophenyl)phosphine complexes of iridium: Molecular structure of trans-IrBr(CO){P(C6F5)(3)}(2)Holloway, JH; Hope, EG; Russell, DR; Saunders, GC; Atherton, MJJournal Article
7-Apr-1997Structural and electronic impact of fluorine in the ortho positions of the phenoxy groups of phenyl-phosphonite and -phosphinite ligands in compounds of platinum-group metalsAtherton, MJ; Fawcett, J; Hill, AP; Holloway, JH; Hope, EG; Russell, DR; Saunders, GC; Stead, RMJJournal Article