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|Title:||Photochemistry with fast sample renewal using cluster beams: formation of rare-gas halides in charge-transfer reactions in NF3-doped rare-gas clusters|
von Haeften, Klaus
Kanaev, A. V.
Castex, M. C.
von Pietrowski, R.
|Citation:||Chemical Physics Letters, 1999, 305 (5-6), pp. 327-333.|
|Abstract:||Charge transfer reactions in free clusters are observed in a photoluminescence study on doped rare-gas clusters (Rg clusters, Rg=Ar, Kr and Xe). Following photoexcitation into the first absorption bands of Rg clusters, fluorescence from free RgF* excimers ejected from the clusters and from Rg2F* excimers localized in the interior of the clusters is observed. The results show that the reaction dynamics in clusters differs considerably from that in the gas and solid phase.|
|Rights:||Copyright © 1999 Elsevier Science B.V.|
|Description:||Metadata only entry|
|Appears in Collections:||Published Articles, Dept. of Physics and Astronomy|
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